AAWSAP DIRD, Metallic Glasses for Aerospace Applications, December 2009
DOW-UAP-D117 · page 23 of 30
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UNCLASSIFIED//FOA &FFI&IAb lltSE 8HL'l • Fatigue resistance (including resistance to both fatigue crack initiation and fatigue crack growth). • Corrosion resistance (including stress-corrosion cracking). • Cost (including raw materials, shaping, and assembly). Figure 9 illustrates the mechanical properties of metallic glasses and metallic glass matrix composites compared with other structural materials. Since weight is a particular concern in aerospace applications, in Figure 9(a) we normalize both yield strength (cry) and stiffness (E) to density (p); two materials with the same specific strength (cry /p) or specific stiffness (E/p) could be used to produce a component with the same overall strength or stiffness, respectively, at the same weight. Materials in the upper-right corner of the plot have the best combination of strength and stiffness for a given weight. Notice that the metallic glasses (and dendritic composites) can be stronger than virtually all crystalline metals, although the stiffness of metallic glasses tends to be somewhat smaller than that of crystalline alloys of similar composition. Figure 9(b) illustrates the damage tolerance of metallic glasses compared with other materials. By plotting the fracture toughness (Klc) against modulus (E), we can also compare the fracture energy (Glc ~ (Klc)2/E) of the materials; the dashed diagonal lines are lines of constant fracture energy. Figure 9(b) reveals several interesting aspects of the damage tolerance of metallic glasses. First, although the fracture toughness of some metallic glasses is comparable to that of crystalline metals, some metallic glasses- most notably those based on iron (Fe) and magnesium (Mg)- are as brittle as any ceramic. Second, both the fracture toughness and the fracture energy of the dendritic metallic glass matrix composites can be superior to those of all but the most fracture-resistant metals. These considerations suggest the dendritic metallic glass matrix composites might indeed find applications as structural materials in aircraft and/or spacecraft. The most obvious applications would be to replace steel in certain components where strength is critical but space is limited. These might include pylon structures and landing gear,38 although it has yet to be demonstrated that the composites can be fabricated in the sizes necessary. Furthermore, the corrosion and stress-corrosion cracking resistance of these materials has not been fully evaluated. 17 UNCLASSIFIED//FOR 8ffle!AL ts5E 014Lt