AAWSAP DIRD, Ultracapacitors as Energy and Power Storage Devices, November 2010
DOW-UAP-D147 · page 3 of 34
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UNCLASSIFIED1fFOR 8ffl@IAL tt9! e"t I Contents Summary................................................................................................................iv Chapter 1: Concept Overview ................................................................................ 1 Batteries and Ultracaps ...................................................................................... 3 History ............................................................................................................... 5 Chapter 2: Materials Technology ........................................................................... 8 Electrolytes ........................................................................................................ 8 Electrodes ............................................................................................................................................................................ 9 Chapter 3: Applications ....................................................................................... 13 Electronics and Telecommunications................................................................ 13 Industrial ......................................................................................................... 13 Transportation ................................................................................................. 14 Aerospace ........................................................................................................ 15 Chapter 4: Recent Developments ........................................................................ 17 CNTs and Advanced Carbons ............................................................................ 17 Thin Films ........................................................................................................ 20 Magnetic Capacitors ......................................................................................... 21 Chapter 5: Future Developments ......................................................................... 25 Chapter 6: Conclusions........................................................................................ 27 Chapter 7: Endnotes ............................................................................................ 28 Figures Figure 1. Ultracaps in Various Configurations . ...................................................... 1 Figure 2. Operation of an Ultracapacitor................................................................3 Figure 3. Ragone Plot.............................................................................................5 Figure 4. Electrolytic Capacitor as Designed and Patented by SOHIO.....................5 Figure 5. Activated Carbon Porosity.....................................................................10 Figure 6. Ultracapacitor Use in a Forklift................................................................14 Figure 7. CNT Forest................................................................................................18 Figure 8. Transmission Electron Microscope Image of Graphene .........................19 Figure 9. Relationship Between Average Pore Size and Normalized Specific Capacitance............................................................................................................. 20 UNCLASSIFIEO/fFOA OFFI&I:.l.b YS& ONLY ii